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It is seen that kp is relatively unaffected until 50% conversion (of monomer to polymer) has been reached, whereas kt has decreased by almost 2 1=2 orders of magnitude in the same span The kp =kt ratio and the polymerization rate simultaneously increase rapidly at rst and then taper off as kp is also affected in the later stages of reaction The attention of the reader is also directed to the data showing the increase in the radical lifetime with increasing conversion At very high conversion (eg, above 50% for the system in Table 3-17), kp becomes suf ciently affected that the Rp = M I 1=2 begins to level off (stage IIIA behavior) or decrease (stage IIIB behavior) Stage IIIB behavior is much more common than stage IIIA.

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Pressed (contacts are opened)

The decrease in rate during stage IIIB, sometimes referred to as the glass or vitri cation effect, can be extremely pronounced depending on the reaction temperature The glass transition temperature of a polymerization reaction mixture increases with conversion of monomer to polymer Polymerization can stop appreciably short of full conversion if the reaction system has a percent conversion whose glass transition temperature exceeds the reaction temperature [Friis and Hamielec, 1976; Mita and Horie, 1987; Sundberg and James, 1978] For example, this occurs in the polymerization of pure methyl methacrylate in Fig 3-15 since the.

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Prime bond yields are represented by two series, neither of which covers the entire period, but which, taken together, provide a reasonable indication of levels and trends: (a) annual average yields of the most popular bond issues of the province of Ontario from 1900 through 1943; and (b) annual average yields of long-term Dominion bonds from 1920 through 1989 The table also contains annual averages from 1917 through 1989 of Canadian real estate mortgage rates These correspond roughly with trust company mortgage rates but were often half a percent or so above life insurance mortgage rates.

TABLE 3-17 Effect of Conversion on the Polymerization of Methyl Methacrylate (22.5 C)a % Conversion 0 10 20 30 40 50 60 70 80

Rate (%/h) 3.5 2.7 6.0 15.4 23.4 24.5 20.0 13.1 2.8

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Short-term Canadian interest rates are represented by three series: (a) annual averages of the discount rate of the Bank of Canada from 1935; (b) annual averages of the Treasury bill tender rate from 1934, which covered all bills until 1955, and after that year covered only three-month bills; and (c) annual averages of the yields of two-year Dominion bonds from 1925 Chart 76 pictures the decennial averages of the province of Ontario bond yields and of the Dominion long-term bond yields Chart 77 compares annual averages of prime US corporate bond yields with annual averages of province of Ontario bond yields from 1900 through 1943 and of Dominion bond yields from 1935 through 1989 The use of Ontario bond yields as a substitute for Dominion bond yields at times when Dominions were not available is justified by the very high credit standing of the province.

t (s) 0.89 1.14 2.21 5.0 6.3 9.4 26.7 79.3 216

Pressing a normally open switch closes the circuit (the same as soldering the end of the wire back in place on the board). Pressing a normally closed switch opens the circuit (the same as de-soldering the wire again and removing it from the board). In other words, switches save a lot of solder. These two examples are of momentary pushbutton switches. Their effect is momentary, or remains as long as you press the button. There are also pushbutton switches that connect or disconnect a circuit every time you push and let go. If your doorbell were connected to a switch like this, the UPS guy would press it once (the doorbell buzzer is now on and the live recording of your dripping sink is ruined), and then walk away thinking you weren t there, doorbell still buzzing (you go downstairs to push the button again; buzzer stops, sink overflows). These are referred to as push on, push off switches. You don t need em for this book s projects, but you can see that they re lots of fun. So, you ll be stocking up on momentary mini pushbutton switches of both types, normally open (N.O. appears on the packaging) and normally closed (N.C., likewise).

Data from Hayden and Melville [1960].

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